This is a category for the characters who appear in season 3 of What's New, Scooby-Doo?.
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- Sam (Diamonds Are a Ghoul's Best Friend)
- Scientist (WNSD Wrestle Maniacs)
- Scooby-Doo Detective Agency
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- Secret Six
- Security kid (E-Scream)
- Shawn
- Shawna (Reef Grief!)
- Sheila (A Scooby-Doo Valentine)
- Skeleton Driver
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- Smash Mouth
- Gary Snipper
- Smith Snipper
- Sparrow Man
- Spice
- Spider (Fright House of a Lighthouse)
- Stacy (A Terrifying Round with a Menacing Metallic Clown)
- Steve (Gentlemen, Start Your Monsters!)
- Toddy Stickfigger
- Storm chasers
- Sugar
- Jonas Sulk
- Super Fans
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